The study of the particular aspects of water purification from the heavy metal ions using the method of nanofiltration

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Authors:

I. M. Trus, orcid.org/0000-0001-6368-6933, National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, Kyiv, Ukraine, e-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.

M. D. Gomelya, orcid.org/0000-0003-1165-7545, National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, Kyiv, Ukraine, e-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.

I. M. Makarenko, orcid.org/0000-0002-7895-2664, National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, Kyiv, Ukraine, e-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.

A. S. Khomenko, orcid.org/0000-0003-3046-6867, National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, Kyiv, Ukraine, e-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.

G. G. Trokhymenko, orcid.org/0000-0002-0835-3551, Admiral Makarov National University of Shipbuilding, Mykolaiv, Ukraine, е-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.

Naukovyi Visnyk Natsionalnoho Hirnychoho Universytetu. 2020, (4): 117-123

https://doi.org/10.33271/nvngu/2020-4/117

повний текст / full article

 

Abstract:

Purpose. To develop highly efficient technologies for deep purification of natural water and wastewater from heavy metal compounds and ions using nanofiltration membranes and complexes to prevent water pollution and protect people and natural objects from the effects of highly toxic pollutants.

Methodology. To remove copper ions from the investigated solutions, potassium ferrocyanide was used as a precipitant; the cationic flocculant Zetag-7547 was used to improve the sedimentation properties of the obtained solid phase. To extract copper, zinc, cadmium, and nickel ions, HEDP and NTMP complexes were used at a concentration of 10–50 mg/dm3. After adding the reagents, the solutions were desalted on a low pressure nanofiltration membrane OPMN-P.

Findings. The optimal conditions for water purification from copper ions by complexation–nanofiltration method were determined. A method for efficient extraction of heavy metals from water to acceptable limits using complexones with subsequent nanofiltration desalination was developed.

Originality. As a result of the conducted research, dependence of productivity of nanofiltration membrane OPMN-P on the pressure, selectivity to ions of copper, zinc, cadmium, nickel and on the degree of selection of permiatewas was established. The dependence of the efficiency of pollutant extraction on the type and consumption of complexoneswas was established. It is shown that the hardness ions, hydrocarbons, chlorides, sulfates reduce the selectivity of the nanofiltration membrane to heavy metal ions, so it is proposed to increase the efficiency of the process to pre-purify water on the anionite AV-17-8 in the basic form. Potassium ferrocyanide was used as a precipitant to remove copper ions from the test solutions, and a solution of the cationic flocculant Zetag-7547 was used to improve the sedimentation properties of the obtained solid phase, followed by purification on a nanofiltration membrane, which allowed increasing the degree of extraction of Cu2+ ions to 99.6 %.

Practical value. The optimal technological parameters of heavy metal ions extraction from aqueous solutions by means of nanofiltration methods using complexons are substantiated in the work. The developed methods for the extraction of heavy metal ions from aqueous solutions allow reducing their concentrations to normative values. Integrated technologies for water purification from heavy metals make it possible to reduce the man-caused impact on the environment by improving water quality and reducing the amount of waste generated, and to improve the environmental situation in the region.

References.

1. Hryniuk, V. I., & Arkhypova, L. M. (2018). Regularity of effects of climatic changes on quality indicators of surface water of the dniester basin. Naukovyi Visnyk Natsionalnoho Hirnychoho Universytetu, (3), 125-133. https://doi.org/10.29202/nvngu/2018-3/17.

2. Malik, L. A., Bashir, A., Qureashi, A., & Pandith, A. H. (2019). Detection and removal of heavy metal ions: A review. Environmental Chemistry Letters, 17(4), 1495-1521.

3. Gorova, A., Pavlychenko, A., Borysovs’ka, O., & Krup­s’ka, L. (2013). The development of methodology for assessment of environmental risk degree in mining regions. Annual Scientific-Technical Colletion – Mining of Mineral Deposit, 207209.

4. Korchemlyuk, M., Arkhipova, L., Kravchynskyi, R. L., & Mykhailyuk, J. D. (2019). Anthropogenic influence from point and diffuse sources of pollution in the upper Prut river basin. Naukovyi Visnyk Natsionalnoho Hirnychoho Universytetu, (1), 125-131. https://doi.org/10.29202/nvngu/2019-1/12.

5. Fashola, M. O., Ngole-Jeme, V. M., & Babalola, O. O. (2016). Heavy metal pollution from gold mines: Environmental effects and bacterial strategies for resistance. International Journal of Environmental Research and Public Health, 13(11), art. no. 1047. https://doi.org/10.3390/ijerph13111047.

6. Dixit, R., Wasiullah, Malaviya, D., Pandiyan, K., Singh, U. B., Sahu, A., Shukla, R., ..., & Paul, D. (2015). Bioremediation of heavy metals from soil and aquatic environment: An overview of principles and criteria of fundamental processes. Sustainability (Switzerland), 7(2), 2189-2212. https://doi.org/10.3390/su7022189.

7. Halysh, V., Sevastyanova, O., Riazanova, A. V., Pasalskiy, B., Budnyak, T., Lindström, M. E., & Кartel, M. (2018). Walnut shells as a potential low-cost lignocellulosic sorbent for dyes and metal ions, Cellulose, 25(8), 4729-4742. https://doi.org/10.1007/s10570-018-1896-y.

8. Benavente, D., Pla, C., Valdes-Abellan, J., & Cremades-Alted, S. (2020). Remediation by waste marble powder and lime of jarosite-rich sediments from Portman Bay (Spain). Environmental Pollution, 264, art. no.114786.

9. Vardhan, K. H., Kumar, P. S., & Panda, R. C. (2019). A review on heavy metal pollution, toxicity and remedial measures: Current trends and future perspectives. Journal of Molecular Liquids, 290, art. no. 111197. https://doi.org/10.1016/j.molliq.2019.111197.

10. Ambiado, K., Bustos, C., Schwarz, A., & Bórquez, R. (2017). Membrane technology applied to acid mine drainage from copper mining. Water Science and Technology, 75(3), 705-715.

11. Gomelya, M. D., Trus, I. M., & Radovenchyk, I. V. (2014). Influence of stabilizing water treatment on weak acid cation exchange resin in acidic form on quality of mine water nanofiltration desalination. Naukovyi Visnyk Natsionalnoho Hirnychoho Universytetu, (5), 100-105.

12. Chen, X., Ren, P., Li, T., Trembly, J. P., & Liu, X. (2018). Zinc removal from model wastewater by electrocoagulation: Processing, kinetics and mechanism. Chemical Engineering Journal, 349, 358-367.

13. Oden, M. K., & Sari-Erkan, H. (2018). Treatment of metal plating wastewater using iron electrode by electrocoagulation process: Optimization and process performance. Process Safety and Environmental Protection, 119, 207-217. https://doi.org/10.1016/j.psep.2018.08.001.

14. Koliehova, A., Trokhymenko, G., Magas, N., Gomelya, N., & Trus, I. (2020). Study of the Process of Electro Evolution of Copper Ions from Waste Regeneration Solutions. Journal of Ecological Engineering, 21(2), 29-38.

15. Kvartenko, O., Sabliy, L., Kovalchuk, N., & Lysytsya, A. (2018). The use of the biological method for treating iron containing underground waters. Journal of Water and Land Development, 39(1), 77-82. https://doi.org/10.2478/jwld-2018-0061.

16. Hu, K., Xu, D., & Chen, Y. (2020). An assessment of sulfate reducing bacteria on treating sulfate-rich metal-laden wastewater from electroplating plant. mailto:This email address is being protected from spambots. You need JavaScript enabled to view it.Journal of Hazardous Materials, 393, art. no.122376.

17. Kyrii, S. O., Kosogina, I. V., Astrelin, I. M., & Obodenko, L. S. (2018). Investigation of the properties of activated carbon modified by wastes of alumina production. VoprosyKhimii i Khimicheskoi Tekhnologii, 2, 70-78.

18. Trus, I., Gomelya, N., Trokhymenko, G., Magas, N., & Hlushko, O. (2019). Determining the influence of the medium reaction and the technique of magnetite modification on the effectiveness of heavy metals sorption. Eastern-European Journal of Enterprise Technologies, 6/10 (102), 49-54.

19. Peng, W., Han, G., Cao, Y., Sun, K., & Song, S. (2018). Efficiently removing Pb(II) from wastewater by graphene oxide using foam flotation. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 556, 266-272. https://doi.org/10.1016/j.colsurfa.2018.08.043.

20. Trus, I. M., Fleisher, H. Y., Tokarchuk, V. V., Gomelya, M. D., & Vorobyova, V. I. (2017). Utilization of the residues obtained during the process of purification of mineral mine water as a component of binding materials. Voprosy Khimii i Khimicheskoi Tekhnologii, (6), 104-109.

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ISSN (print) 2071-2227,
ISSN (online) 2223-2362.
Journal was registered by Ministry of Justice of Ukraine.
Registration number КВ No.17742-6592PR dated April 27, 2011.

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