Predicting changes in the sulfur content during steam coal preparation and the level of sulfur dioxide emissions when its combustion

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Authors:


M.V.Chernyavskyy, orcid.org/0000-0003-4225-4984, Coal Energy Technology Institute of National Academy of Sciences of Ukraine, Kyiv, Ukraine, e-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.

A.M.Voronov, orcid.org/0000-0003-4538-7870, Separate division Ukrainian Research and Design Institute for Coal Preparation and Briquetting of the State Enterprise Scientific and Technical Center VUHLEINNOVATSIIA, Dnipro, Ukraine, e-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.

O.V.Moiseienko, orcid.org/0000-0002-8081-6960, Separate division Ukrainian Research and Design Institute for Coal Preparation and Briquetting of the State Enterprise Scientific and Technical Center VUHLEINNOVATSIIA, Dnipro, Ukraine, e-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.

S.H.Duliienko, orcid.org/0000-0002-2811-8882, Coal Energy Technology Institute of National Academy of Sciences of Ukraine, Kyiv, Ukraine, e-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.

T.M.Monastyriova, orcid.org/0000-0001-8199-2416, Coal Energy Technology Institute of National Academy of Sciences of Ukraine, Kyiv, Ukraine, This email address is being protected from spambots. You need JavaScript enabled to view it.


повний текст / full article



Naukovyi Visnyk Natsionalnoho Hirnychoho Universytetu. 2021, (2): 032 - 039

https://doi.org/10.33271/nvngu/2021-2/032



Abstract:



Purpose.
Development of a method and forecast estimation of sulfur dioxide emission reduction during combustion of steam coal by regulating its quality during coal preparation.


Methodology.
Study on sulfur content in coal using sieve, fractional analysis, analysis of ash and total sulfur content. Forecasting of sulfur content in concentrate according to the developed calculation method. Production tests at the coal preparation plant. Forecasting of the level of SO2 emissions during pulverized coal combustion according to the developed calculation method.


Findings.
The distribution of sulfur content of Ukrainian steam bituminous coal by size classes depending on ash content is investigated; the proximity of sulfur content to the linear dependance on the ash content of the run-of-mine coal, rock-free substance, rock and concentrate is proved. The calculations of the level of SO2 emissions during pulverized combustion of coal and its cleaned products taking into account their elemental composition is performed, and the linear dependence of the level of SO2 emissions on the total sulfur content to lower heating value (LHV) ratio is proved. Based on the obtained results, methods are developed for determining the expected sulfur content in the concentrate and the forecasted level of SO2 emissions during its combustion; the optimal depth of preparation for the coal from various mines is determined by the criterion of compliance of the SO2 emission level with the current environmental standards.


Originality.
Proximity of the sulfur content to the linear dependence on the ash content of the run-of-mine coal, rock-free substance, rock and concentrate is proved. The linear dependence of the level of SO2 emissions on the ratio of the total sulfur content to LHV during pulverized combustion of coal and its clean products is proved.


Practical value.
A method has been developed for determining the expected sulfur content in the products of coal preparation by jigging, taking into account the allowable content of the high-density fraction in the concentrate and adding dense slimes to the coal preparation products. A method has been developed for determining the predicted level of SO2 emissions during their combustion. The optimal depth of the coal preparation for coal from various mines has been determined by the criterion of compliance of the level of SO2 emissions with the current environmental standards.



Keywords:
steam coal, sulfur content, coal preparation, pulverized combustion, sulfur dioxide emissions

References.


1. Chernyavskyy, M.V., Dunayevska, N.I., Prvalov, O.Yu., & Miroshnichenko, Ye.S. (2020). Scientific basis and technologies of anthracite replacement at thermal power plants. Naukovyi Visnyk Natsionalnoho Hirnychoho Universytetu, (3), 33-40. https://doi.org/10.33271/nvngu/2020-3/033.

2. National Emissions Reduction Plan for Large Combustion Plants. Adopted by the direction of Cabinet of Ministers of Ukraine of 08.11.2017 No. 796-r. Retrieved from https://zakon.rada.gov.ua/laws/show/796-2017-%D1%80#Text.

3. Hower, J. (2016). Coal. In Kirk-Othmer Encyclopedia of Chemical Technology, John Wiley & Sons. https://doi.org/10.1002/0471238961.0315011222151818.a01.pub3.

4. Speight, J.G. (2013). The Chemistry and Technology of Coal. (3rd ed.) CRC Press, Taylor & Francis Group, Boca Raton, Florida. https://doi.org/10.1201/b12497.

5. Keppeler, J.G. (2015). Coals, Lignite, and Peat. In Kutz,M. (Ed.) (2015). Mechanical Engineers Handbook, Fourth Edition. John Wiley & Sons, Inc. https://doi.org/10.1002/9781118985960.meh420.

6. Kizilshtein, L.Ya. (1975). Genesis of sulfur in coals. Rostov na Donu: Publishing House of Rostov State University.

7. Dolgiy, V.Ya., Krivchenko, A.A., & Shamalo, M.D. (2000). The content of total sulfur in coal seams in the mines of Ukraine. Coal of Ukraine, (1), 10-12. Retrieved from http://masters.donntu.org/2009/feht/semkovskiy/library/article9.htm.

8. Calkins, W.H. (1994). The chemical forms of sulfur in coal: a review. Fuel, 73(4). 475-484. https://doi.org/10.1016/0016-2361(94)90028-0.

9. Shpirt, M.Ya., Kler, V.R., & Pertsikov, I.Z. (1990). Inorganic components of solid fuels. Moscow: Chemistry. ISBN5-7245-0578-9.

10. Sidorovych, Ya.Y., Haivanov, V.I., Pishchiev, S.V., Sipyak, O.I., & Sidorovych, M.Ya. (1997). Problems of desulfurization of coal and utilization of coal sulfur. Coal of Ukraine, (2-3), 16-27.

11. Demirbas, A., & Balat, M. (2004). Coal Desulfurization via Different Methods. Energy Sources, 26(6), 541-550. https://doi.org/10.1080/00908310490429669.

12. Wang, M., Song, D., Zheng, B., & Finkelman, R.B. (2008). The Studying of Washing of Arsenic and Sulfur from Coals Having Different Ranges of Arsenic Contents. Annals of the New York Academy of Sciences, 1140(1), 321-324. https://doi.org/10.1196/annals.1454.018.

13. Bogenschneider, B., Jung, R.G., & Klein, J. (2005). Desulfurization of Coal. In Biopolymers Online: Biology, Chemistry, Biotechnology, Applications. Part 1. Lignin, Humic Substances and Coal. Wiley-VCH Verlag GmbH. https://doi.org/10.1002/3527600035.bpol1015.

14. Zhang, B., Zhao, Y., Zhou, Ch., Duan, Ch., & Dong, L. (2015). Fine Coal Desulfurization by Magnetic Separation and the Behavior of Sulfur Component Response in Microwave Energy Pretreatment. Energy and Fuels, 29(2):150109100223007. https://doi.org/10.1021/ef502003g.

15. Zhang, B., Zhou, C., Zhao, Y., Cai., L., & Fan, X. (2017). Fine coal desulphurization and microwave energy absorption behaviour by microwave magnetic separation. The Canadian Journal of Chemical Engineering, 95, 1156-1163. https://doi.org/10.1002/cjce.22769.

16. Laptienko, A.L., Rekun, V.V., Taryanik, A.V., Saranchuk, V.I., & Shendrik, T.G. (2003). Method of deep purification of coal and coal wastes from ash and sulfur. Coke and chemistry, (8), 14-18.

17. Merkhut, A., & Tymoschuk, M. (2019). Modernization of coal mills using the HER-ART technology, a method of extending the service life and reducing emissions. 15th International scientific-practical. conf. Coal thermal energy: ways of reconstruction and development: Collection of Science works, (pp. 85-88). Kyiv: IVE NAS of Ukraine.

18. Chiang, S.H., & Cobb, J.T. (2000). Coal Conversion Processes, Cleaning and Desulfurization. In Kirk-Othmer Encyclopedia of Chemical Technology. John Wiley & Sons. https://doi.org/10.1002/0471238961.0312050103080901.a01.

19. Cavallaro, J.A., Deurbrouck, A.W., Killmeyer, R.P., Fuchs, W., & Jacobsen, P.S. (1991). Sulfur and Ash Reduction Potential and Selected Chemical and Physical Properties of United States Coals. DOE/PETC-91/6. Retrieved from https://www.osti.gov/servlets/purl/5435690.

20. Ali, A., Srivastava, S.K., & Haque, R. (1992). Studies on the Simultaneous Desulphurization and Demineralization of Coal. Fuel, 71, 835-839.

21. Speight, J.G. (2013). Recovery, Preparation, and Transportation. In Coal-Fired Power Generation Handbook, (pp. 69-126). Scrivener Publishing LLC. https://doi.org/10.1002/9781118739457.ch3.

22. Filippenko, Yu.N., Rudavina, E.V., Sklyar, P.T., & Chernyavsky, N.V. (2010). The contribution of mineral mass to the observed values of the volatile yield and the elemental composition of coal. Enrichment of minerals: scientific and technical collection, 40(81), 26-31. Retrieved from http://ir.nmu.org.ua/bitstream/handle/123456789/152686/6.pdf?sequence=1&isAllowed=y.

23. Volchin, I.A., & Gaponich, L.S. (2016). Calculation of parameters of flue gases of coal thermal power plants on the basis of characteristics of solid fuel. Energy technologies and resource saving, (1), 49-56.

24. Chernyavskyy, M.V. (2020). The method of determining the expected sulfur content in the coal preparation products. (Ukrainian Patent No. 143011). Ukraine.

25. Chernyavskyy, M.V., Dulienko, S.G., & Monastyreva,T.M. (2020). The method of express determination of predicted level of sulfur dioxide emissions when pulverized combustion of bituminous coal. (Ukrainian Patent No. 143014). Ukraine.

 

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ISSN (print) 2071-2227,
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Journal was registered by Ministry of Justice of Ukraine.
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