Origin of the over consumption of cyanide during the leaching of the Amesmessa gold ore

User Rating:  / 0
PoorBest 

Authors:


M.Y.Baghdadi, orcid.org/0009-0007-5807-9590, University of Bejaia, Faculty of Exact Sciences, Laboratory of Physico-Chemistry Materials and Catalysis (LPCMC), Bejaia, Algeria; University of Bejaia, Faculty of Technology, Department of Mining and Geology, Bejaia, Algeria

Z.Chafi*, orcid.org/0000-0002-7956-0160, University of Bejaia, Faculty of Exact Sciences, Laboratory of Physico-Chemistry Materials and Catalysis (LPCMC), Bejaia, Algeria; University of Bejaia, Faculty of Technology, Department of Mining and Geology, Bejaia, Algeria

M.Louz, orcid.org/0009-0009-0731-5236, University of Saad Dahlab, Faculty of Science and Technology, Department of Process Engineering,  Blida, Algeria

T. Tahri, orcid.org/0000-0002-3953-9914, University of Bejaia, Faculty of Technology, Laboratory of Materials Technology and Process Engineering (LTMGP), Bejaia, Algeria

M.E.A.Benamar, orcid.org/0000-0003-0787-6913, University of Ahmed Draia, Faculty of Materials Science, Mathematics and Computer Science, Department of Materials Science, Adrar, Algeria

S.Bellucci, orcid.org/0000-0003-0326-6368, INFN-Laboratori Nazionali di Frascati, Rome, Italy; National Institute of Materials Physics, Bucharest, Romania

* Corresponding author e-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.


повний текст / full article



Naukovyi Visnyk Natsionalnoho Hirnychoho Universytetu. 2025, (2): 026 - 032

https://doi.org/10.33271/nvngu/2025-2/026



Abstract:



Purpose. Physicochemical characterization of four gold ores from the Amesmessa deposit centre (western Hoggar, in the south of Algeria) to determine the mineralogical and chemical composition of the ore body in the depth zone and ore cyanidation behaviour. The principle is to compare the gold recovery and the cyanide consumption rates at the end of the leaching process. The purpose of this test is to detect the possible presence of cyanogenic elements in the mineralised zone.


Methodology. The samples were crushed and analysed using many techniques, such as x-ray diffraction (XRD), Infrared spectroscopy (IR), and x-ray fluorescence spectrometry (XRF). The leaching tests were carried out over a 24-hour period. Two different types of gold ore were used.


Findings. Gold is distributed throughout all the facies making up the orebody, including the schistose structure. Ore characterization by XRD revealed that quartz, dolomite, calcite, phengite, and pyrite are the major ore phases at depth. The quartz facies and the altered one located in the depth zone are rich in gold 163 and 10.8 g/t respectively. XRF characterization reveals that the schist facies are rich in iron and carbonates (23 % Fe and 14 % Ca). Infrared spectroscopy is a powerful and efficient tool for distinguishing the nature of the facies. Ore from altered facies shows overconsumption of cyanide, with an overage of 48 %, compared to the 86 % required for quartz ore. The presence of cyanide over-consuming elements leads to low overage in the altered ore.


Originality. The application of rapid and reliable spectroscopy, such as infrared spectroscopy in combination with XRD and XRF, allowed understanding the mineralogy of the different facies in the deep zone of the Amesmessa deposit.


Practical value. The knowledge of the facies mineralization is an important parameter for determining recovery and cyanide consumption during the leaching tests, anticipating the presence of cyanide overconsumption elements.



Keywords: Amesmessa deposit, gold ore, characterisation, cyanidation, gold recovery, mineralogy

References.


1. Zhang, J., Tian, S., Liu, R., Liu, X., Guo, J., & Yang, Y. (2024). Efficient and selective extraction of gold from acidic leaching solutions using novel guanidinium ionic liquid. Journal of Molecular Liquids, 414, 126033. https://doi.org/10.1016/j.molliq.2024.126033

2. Karppinen, A., Seisko, S., Nevatalo, L., Wilson, B. P., Yliniemi, K., & Lundström, M. (2024). Gold recovery from cyanidation residue by chloride leaching and carbon adsorption – Preliminary results from CICL process. Hydrometallurgy, 226, 106304. https://doi.org/10.1016/j.hydromet.2024.106304

3. Alkloos, B., & Aydoğan, S. (2024). Cyanidation of tailings in artisanal small-scale gold mining at Arbaat Region in Red Sea State, Sudan. Scientific Mining Journal, 62(4), 191-196. https://doi.org/10.30797/madencilik.1416245

4. Roca, A., Cruells, M., Patiño, F., Rivera, I., & Plata, M. (2006). Kinetic model for the cyanidation of silver ammonium jarosite in NaOH medium. Hydrometallurgy, 81(1), 15-23. https://doi.org/10.1016/j.hydromet.2005.09.004

5. Rees, K. L., & Van Deventer, J. S. J. (2000). The mechanism of enhanced gold extraction from ores in the presence of activated carbon. Hydrometallurgy, 58(2), 151-167. https://doi.org/10.1016/S0304-386X(00)00130-4

6. Wu, B., Shang, H., Wen, J. K., Liu, M. L., Zhang, Q. D., & Cui, X. L. (2020). Well-controlled stirring tank leaching to improve bio-oxidation efficiency of a high sulfur refractory gold concentrate. Journal of Central South University, 27(5), 1416-1423. https://doi.org/10.1007/s11771-020-4377-z

7. Marsden, J., & House, I. (2006). The chemistry of gold extraction. SME. ISBN-13: 978-0-87335-240-6 ISBN-10: 0-87335-240-8

8. Aissa, D. E., & Marignac, C. (2017). Controls on gold deposits in Hoggar, Tuareg Shield (Southern Algeria). Journal of African Earth Sciences, 127, 136-145. https://doi.org/10.1016/j.jafrearsci.2016.09.002

9. Golik, V. I., Klyuev, R. V., Martyushev, N. V., Zyukin, D. A., & Karlina, A. I. (2023). Prospects for return of valuable components lost in tailings of light metals ore processing. Metallurgist, 67(1), 96-103. https://doi.org/10.1007/s11015-023-01493-5

10.      Valier. D. I., & Abidova, N. A. (2020). Feature of sample preparation method by Richards-Chette formula in the study of representativeness and reliability of core sampling at Chukurkuduk deposit (Muntov ore field). Nauch. i Prakt. Issled, 2/4(25), 4-7.

11.      Sivakumar, S., Ravisankar, R., Chandrasekaran, A., & Jebakumar, J. P. P. (2013). FT-IR Spectroscopic studies on coastal sediment samples from nagapattinum district, Tamilnadu, India. International Research Journal of Pure and Applied Chemistry, 3(4), 366. https://doi.org/10.9734/IRJPAC/2013/4265

12.      Ojima, J. (2003). Determining of crystalline silica in respirable dust samples by infrared spectrophotometry in the presence of interferen­ces. Journal of Occupational Health, 45(2), 94-103. https://doi.org/10.1539/joh.45.94

13.      Boussaa, S. A., Kheloufi, A., Zaourar, N. B., Kefaifi, A., & Kerkar, F. (2016, July). Characterization of silica quartz as raw material in photovoltaic applications. In AIP Conference Proceedings, 1758(1). AIP Publishing. https://doi.org/10.1063/1.4959439

14.      Boussaa, S. A., Kheloufi, A., & Zaourar, N. B. (2017). Characterization of impurities present on Tihimatine (Hoggar) quartz, Algeria. Journal of African Earth Sciences, 135, 213-219. https://doi.org/10.1016/j.jafrearsci.2017.09.001

15.      Nayak, P. S., & Singh, B. K. (2007). Instrumental characterization of clay by XRF, XRD and FTIR. Bulletin of materials science, 30(3), 235-238. https://doi.org/10.1007/s12034-007-0042-5

16.      Ji, J., Ge, Y., Balsam, W., Damuth, J. E., & Chen, J. (2009). Rapid identification of dolomite using a Fourier Transform Infrared Spectrophotometer (FTIR): A fast method for identifying Heinrich events in IODP Site U1308. Marine Geology, 258(1-4), 60-68. https://doi.org/10.1016/j.margeo.2008.11.007

17.      Bandfield, J. L., Glotch, T. D., & Christensen, P. R. (2003). Spectroscopic identification of carbonate minerals in the Martian dust. Science, 301(5636), 1084-1087. https://doi.org/10.1126/science.1088054

18.      Chruszcz-Lipska, K., Solecki, M. L., Trzewik, B., Maruta, M., Wartak, J., & Zagrajczuk, D. (2021). IR spectroscopy as a fast method of determining carbonate content in the Sarmatian–Badenian sandstone reservoirs: A case study from the Carpathian Foredeep (Poland). Geologica Carpathica, 72(4). https://doi.org/10.31577/GeolCarp.72.4.4

19.      Mookherjee, M., & Redfern, S. A. T. (2002). A high-temperature Fourier transform infrared study of the interlayer and Si–O-stretching region in phengite-2M1. Clay Minerals, 37(2), 323-336. https://doi.org/10.1180/0009855023720036

20.      Elbashir Siddig, F., Elbashir, A. A., Lepper, V., & Hussein, A. (2018). Spectroscopic approach for characterization of archaeological potsherds excavated from some Neolithic sites from Sudan. International journal of experimental spectroscopic techniques, 3(2), 1-11. https://doi.org/10.35840/2631-505X/8517

21.      Fagbohun, B. J., Omitogun, A. A., Bamisaiye, O. A., & Ayoola, F. J. (2020). Gold potential of the Pan African Trans-Sahara belt and prospect for further exploration. Ore Geology Reviews, 116, 103260. https://doi.org/10.1016/j.oregeorev.2019.103260

22.      Kianinia, Y., Khalesi, M. R., Abdollahy, M., Hefter, G., Senanayake, G., Hnedkovsky, L.,..., & Shahbazi, M. (2018). Predicting cyanide consumption in gold leaching: a kinetic and thermodynamic modeling approach. Minerals, 8(3), 110. https://doi.org/10.3390/min8030110

23.      Ahtiainen, R., Liipo, J., & Lundström, M. (2021). Simultaneous sulfide oxidation and gold dissolution by cyanide-free leaching from refractory and double refractory gold concentrates. Minerals Engineering, 170, 107042. https://doi.org/10.1016/j.mineng.2021.107042

24.      Han, J., Li, X., & Dai, S. (2020). Electrochemical influence of quartz on cyanide leaching of gold. Chemical Physics Letters, 739, 136997. https://doi.org/10.1016/j.cplett.2019.136997

25.      Bas, A. D., & Larachi, F. (2019). The effect of flotation collectors on the electrochemical dissolution of gold during cyanidation. Mine­rals Engineering, 130, 48-56. https://doi.org/10.1016/j.mineng.2018.10.003

26.      Larrabure, G., & Rodríguez-Reyes, J. C. F. (2021). A review on the negative impact of different elements during cyanidation of gold and silver from refractory ores and strategies to optimize the leaching process. Minerals Engineering, 173, 107194. https://doi.org/10.1016/j.mineng.2021.107194

27.      Tremolada, J., Dzioba, R., Bernardo-Sánchez, A., & Menéndez-Aguado, J. M. (2010). The preg-robbing of gold and silver by clays during cyanidation under agitation and heap leaching conditions. International Journal of Mineral Processing, 94(1-2), 67-71. https://doi.org/10.1016/j.minpro.2009.12.001

28.      Yang, H. Y., Qian, L. I. U., Song, X. L., & Dong, J. K. (2013). Research status of carbonaceous matter in carbonaceous gold ores and bio-oxidation pretreatment. Transactions of Nonferrous Metals Society of China, 23(11), 3405-3411.  https://doi.org/10.1016/S1003-6326(13)62881-2

29.      Rees, K. L., & Van Deventer, J. S. J. (2000). Preg-robbing phenomena in the cyanidation of sulphide gold ores. Hydrometallurgy, 58(1), 61-80. https://doi.org/10.1016/S0304-386X(00)00131-6

30.      Acar, S. (2016). Process development metallurgical studies for gold cyanidation process. Minerals & Metallurgical Processing, 33(4), 161-171. https://doi.org/10.1002/adma.201506171

 

Visitors

9666397
Today
This Month
All days
7837
805827
9666397

Guest Book

If you have questions, comments or suggestions, you can write them in our "Guest Book"

Registration data

ISSN (print) 2071-2227,
ISSN (online) 2223-2362.
Journal was registered by Ministry of Justice of Ukraine.
Registration number КВ No.17742-6592PR dated April 27, 2011.

Contacts

D.Yavornytskyi ave.,19, pavilion 3, room 24-а, Dnipro, 49005
Tel.: +38 (066) 379 72 44.
e-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.
You are here: Home About the journal concept of the journal EngCat Archive 2025 Content №2 2025 Origin of the over consumption of cyanide during the leaching of the Amesmessa gold ore