Dephosphorization of oxidized iron ore from Gara Djebilet, Tindouf (Algeria)

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Authors:

S.Badjoudj, Badji Mokhtar University, Annaba, Algeria, e-mail: ecoteam15@yahoo.fr

A.Idres, Dr. Sc. (Tech.), Badji Mokhtar University, Annaba, Algeria.

A.Benselhoub, PhD, Badji Mokhtar University, Annaba, Algeria.

M.Bounouala, Dr. Sc. (Tech.), Badji Mokhtar University, Annaba, Algeria.

Abstract:

Purpose. The study of this scientific work concerns the treatment of the oolitic iron ore deposit of Gara Djebilet, Tindouf, Algeria. Chemical and mineralogical analyzes performed on the representative sample taken from the studied area show high presence of phosphorus oxide P2O5. This negatively affects the quality of iron and steel products. Quality improvement and reducing the content of impurities in the studied iron ore were the main objectives of the present research study.

Methodology. To identify this ore, characterization is carried out on polished sections and thin blades, as well as a chemical analysis of the initial sample, an XRD analysis of different size fractions of the initial sample, a chemical analysis of major elements of iron ore from Gara Djebilet by XRF and quantitative analyses by EDX 74. Tests are conducted on different types of roast slices with grain sizes of (-0250 + 0.125; -0.125 + 0.063; 0.045 + -0063 and -0045 + 0.00) mm. Calcium chloride CaCl2 additional to the dose ratio with iron ore: 10:90, 15:85, 20:80, 25:75 at different temperatures, 600 ºC, 700, 800 and 900 ºC. After cooling, the roasted mass is analyzed with XRF.

Findings. Different size fractions of the crude sample were analyzed by XRD. The obtained results show that the mineralogical composition comprises: hematite, phosphorus, silica, alumina and lime. The best results are achieved with the following parameters: the particle size range - 0.063 + 0.045 mm, upon the complete release of the useful component of its matrix with a P2O5 content equal to 0.06 % and Fe2O3 equal to 61.67 %. The effect of CaCl2 (alkaline earth metal additive) on phosphorus during the roasting of iron ore in the ratio of 20 % CaCl2 and 80 % Fe2O3 contributes greatly to the reduction of phosphorus in the ore from Gara Djebilet, Tindouf, Algeria.

Originality. The Gara Djebilet iron deposit has not been exploited yet due to its high phosphorus content. The originality of this research work resides in the application of the roasting process using calcium chloride at different grain sizes, temperatures and concentrations.

Practical value. This method allows us to reduce the phosphorus to an acceptable level for the steel industry. The present process is simple, economical and does not require investment in industrial equipment.

References:

1. Ionkov, K., Gaydardzhiev, S., Bastin, D., de Araujo, A. C. and Lacoste, M., 2012. Removal of phosphorous through roasting of oolitic iron ore with alkaline earth additives. In: Proceedings of the XXVI International Mineral Processing Congress, New Delhi. pp. 2194‒2205.

2. Obot, O. W. and Anyakwo, C. N., 2012. Removal of phosphorus from Nigerias Agbaja iron ore through the degradation ability of Micrococcus species. International Journal of Water Resources and Environmental Engineering, 4(4), pp. 114‒119.

3. Obiorah, S. M. O., Menkiti, M. C. and Nnuka, E. E., 2011. Beneficiation Processing of Agbaja Iron Ore by Chemical Leaching Technique. New York Science Journal, 4(5), pp. 22‒27.

4. Edwards, C. I., Fisher-White, M. J., Lovel, R. R. and Sparrow, G. J., 2011. Removal of Phosphorus from Australian iron Ores. Iron Ore 2011, pp. 403‒412.

5. Zhu, D. Q., Chun, T. J., Pan, J., Lu, L. M. and He, Z., 2013. Upgrading and dephosphorization of Western Australian iron ore using reduction roasting by adding sodium carbonate. International Journal of Minerals, Metallurgy, and Materials, 20(6), pp. 505‒513.

6. Ionkov, K., Gaydardzhiev, S., de Araujo, A. C., Bastin, D. and Lacoste, M., 2013. Amenability for processing of oolitic iron ore concentrate for phosphorus removal. Minerals Engineering, 46, pp. 119‒127.

7. Yang, M., Zhu, Q. S., Fan, C. L., Xie, Z. H. and Li, H. Z., 2015. Roasting-induced phase change and its influence on phosphorus removal through acid leaching for high-phosphorus iron ore. International Journal of Minerals, Metallurgy, and Materials, 22(4), pp. 346‒352.

8. Li, Y. L., Sun, T. C., Xu, C. Y. and Liu, Z. H., 2012. New dephosphorizing agent for phosphorus removal from high-phosphorus oolitic hematite ore in direct reduction roasting. Journal of Central South University (Science and Technology), 3, рр. 827‒834.

9. Xu, C. Y., Sun, T. C., Jue, K., Li, Y. L., Mo, X. L. and Tang, L. G., 2012. Mechanism of phosphorus removal in beneficiation of high phosphorous oolitic hematite by direct reduction roasting with dephosphorization agent. Transactions of Nonferrous Metals Society of China, 22(11), pp. 2806‒2812.

10. Tang, H. Q., Guo, Z. C. and Zhao, Z. L., 2010. Phosphorus removal of high phosphorus iron ore by gasbased reduction and melt separation. Journal of Iron and Steel Research, International, 17(9), pp. 1‒6.

11. Bersi, M., Saibi, H. and Chabou, M. C., 2016. Aerogravity and remote sensing observations of an iron deposit in Gara Djebilet, southwestern Algeria. Journal of African Earth Sciences, 116, рр. 134‒150.

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