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The use of brown coal in Ukraine to obtain water-soluble sorbents

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Category: Content №4 2022

Last Updated on 29 August 2022

Published on 30 November -0001

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Authors:

A.O.Sinitsyna, orcid.org/0000-0003-1031-8605, National Technical University Kharkiv Polytechnic Institute, Kharkiv, Ukraine, e-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.

P.V.Karnozhitskiy, orcid.org/0000-0001-6019-8432, National Technical University Kharkiv Polytechnic Institute, Kharkiv, Ukraine, e-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.

D.V.Miroshnichenko, orcid.org/0000-0002-6335-8742, National Technical University Kharkiv Polytechnic Institute, Kharkiv, Ukraine, e-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.

D.Yu.Bilets, orcid.org/0000-0002-1521-826X, National Technical University Kharkiv Polytechnic Institute, Kharkiv, Ukraine, e-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.

повний текст / full article

Naukovyi Visnyk Natsionalnoho Hirnychoho Universytetu. 2022, (4): 005 - 010

https://doi.org/10.33271/nvngu/2022-4/005

Abstract:

Purpose. To develop a method of using salts of humic acids obtained from brown coal of Ukraine for sorption of heavy metal ions and their extraction using ultrafiltration membranes.

Methodology. Unique laboratory equipment has been developed to determine the sorption capacity of humic substances with a concentration of 0 to 20 mg/l in relation to heavy metal ions (Cu²⁺, Pb²⁺, Cd²⁺, Hg²⁺, Zn²⁺, Co²⁺) with a concentration of 5 mg/l. The results of proximate and ultimate analyzes, as well as infrared and optical emission spectroscopy were used to assess the quality of brown coal, humic substances and the solution of humic substances with heavy metal ions.

Findings. Ukrainian brown coal of Oleksandriia geological-industrial district contains a large amount (about 80%) of humic acid, which is the basis for obtaining effective water-soluble sorbents. It is proved that humic substances obtained from brown coal of Ukraine allow binding up to 99% of heavy metal ions in complexes. The most optimal concentration of humic substances in terms of their concentration and selectivity of heavy metal ions extraction is 5 mg/l.

Originality. The possibility of practical using of humic substances obtained from brown coal of Ukraine for sorption of heavy metal ions has been proved. As ultrafiltration membranes, UF-20-PAN membranes are used, which are porous polymer films based on polyacrylonitrile with a pore size of 20 m, the working surface area of the membrane is 28.26 10^-4 m².

Practical value. The introduction of the developed technology will allow, firstly, restoring the practical use of large deposits of brown coal in Ukraine, and secondly, introducing deep treatment of industrial and wastewater.

Keywords: brown coal, sorption, heavy metal ions, membrane, humic substances, IR spectroscopy

References.

1. Mineralni resursy Ukrainy (n.d.). Retrieved from https://minerals-ua.info/.

2. Gunka, V., Shved, M., Prysiazhnyi, Y., Pyshyev, S., & Miroshnichenko, D. (2019). Lignite oxidative desulphurization: notice 3 process technological aspects and application of products. International journal of Coal Science and Technology, 6, 63-73. https://doi.org/10.1007/s40789-018-0228-z.

3. Lebedev, V., Miroshnichenko, D., Zhang Xiaobin, Pyshyev, S., & Savchenko, D. (2021). Technological properties of polymers obtained from humic acids of Ukrainian lignite. Petroleum and coal, 63(3), 646-654. Retrieved from https://vurup.sk/wp-content/uploads/2021/08/PC-X_Miroshnichenko_31_rev1.pdf.

4. Bilets, D., Miroshnichenko, D., Ryshchenko, J., & Rudniev, V. (2021). Determination of material balance gasification of heavy coal tars with lignite and walnut shell. Petroleum and coal, 63(1), 85-90. Retrieved from https://www.vurup.sk/wp-content/uploads/2021/01/PC-X_Miroschnichenko_202.pdf.

5. Amoah-Antwi, C., Kwiatkowska-Malina, J., Thornton, S.F., Fenton, O., Malina, G., & Szara, E. (2020). Restoration of soil quality using biochar and brown coal waste: A review. Science of The Total Environment, 722, 137852. https://doi.org/10.1016/j.scitotenv.2020.137852.

6. Narges Esfandiar, Rominder Suri, & Erica R. McKenzie (2022). Competitive sorption of Cd, Cr, Cu, Ni, Pb and Zn from stormwater runoff by five low-cost sorbents; Effects of co-contaminants, humic acid, salinity and pH. Journal of Hazardous Materials, 423(Part A), 126938. https://doi.org/10.1016/j.jhazmat.2021.126938.

7. Ayad A.H. Faisal, Mohammed B. Abdul-Kareem, Alaa Kareem Mohammed, Mu Naushad, Ayman A. Ghfar, & Tansir Ahamad (2020). Humic acid coated sand as a novel sorbent in permeable reactive barrier for environmental remediation of groundwater polluted with copper and cadmium ions. Journal of Water Process Engineering, 36, 101373. https://doi.org/10.1016/j.jwpe.2020.101373.

8. Zhon, H.-Z., Liu, P., Su, X.-Ch., Liao, Ya.-H., Lei, N.-Sh., Liang,Yo.-H., , & Tang, Ya. (2017). Low-cost humic acid-bonded silica as an effective solid-phase extraction sorbent for convenient determination of aflatoxins in edible oils. Analytica Chimica Acta, 970, 38-46. https://doi.org/10.1016/j.aca.2017.02.029.

9. Esmaeilian, A., & OShea, K.E. (2022). Application of dimensional analysis in sorption modeling of the styryl pyridinium cationic dyes on reusable iron based humic acid coated magnetic nanoparticles. Chemosphere, 286(Part 2), 131699. https://doi.org/10.1016/j.chemosphere.2021.131699.

10. Noli, F., Fedorcea, V., Misaelides, P., Cretescu, I., & Kapnisti, M. (2021). Cesium and Barium removal from aqueous solutions in the presence of humic acid and competing cations by a Greek bentonite from Kimolos Island. Applied Radiation and Isotopes, 170, 109600. https://doi.org/10.1016/j.apradiso.2021.109600.

11. Zhang, Ya., Fein, J.B., Yu, Q., Liu, D., Feng, Yu., Zu, B., & Zheng, Ch. (2021). Surface complexation modeling of the effects of dissolved inorganic carbon on absorption of U (VI) onto Fe₃O₄ nanoparticles coated with lignite humic acid. Colloids and Surface A: Physiochemical and Engineering Aspects, 629, 127260. https://doi.org/10.1016/j.colsurfa.2021.127260.

12. Sarlaki Ehsan, Sharif Paghaleh Ali, Kianmehr Mohammad Hossein, & Asefpour Vakilian Keyvan (2021). Valorization of lignite wastes into humic acids: Process optimization, energy efficiency and structural features analysis. Renewable Energy, 163, 105-122. https://doi.org/10.1016/j.renene.2020.08.096.

13. Wang, Yu., Ma, Y.-y., Mo, W.-L., Gong, W.-T., Ma, F.-Yu., Wei,X.-Yo., Fan, X., & Zhang, S.-P. (2021). Functional groups of sequential extracts and corresponding residues from Hefeng subbituminous coal based on FT-IR analysis. Journal of Fuel Chemistry and Technology, 49(7), 890-901. https://doi.org/10.1016/S1872-5813(21)60055-5.

14. Wang, J., Tian, L., Li, G., Zhao, X., Liang, Yi., & Yu, J. (2021). Construction of vitrinite molecular structures based on ¹³C NMR and FT-IR analysis: fundamental insight into coal thermoplastic properties. Fuel, 300, 120981. https://doi.org/10.1016/j.fuel.2021.120981.

15. Zhao, Ya., Xing, Ch., Shao, Ch., Chen, G., Sun, Sh., Chen, G., , & Guo, Sh. (2020). Impacts of intrinsic alkali and alkaline earth metals on chemical structure of low-rank coal char: Semi-quantitative results based on FT-IR structure parameters. Fuel, 278, 118229. https://doi.org/10.1016/j.fuel.2020.118229.

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